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ASTM F436 Section 2.1 allows Type 3 weathering steel washers to be supplied either to a fixed chemistry envelope (Type 3A in F436 Table 1) OR to a Corrosion Index (CRI) of 6 or higher computed from the Legault-Leckie formula in ASTM Guide G101. The CRI option gives the supplier flexibility to vary chemistry within a wider band as long as the calculated corrosion-resistance index meets the 6.0 threshold. This page documents the Legault-Leckie formula, the CRI 6 cut-off, and when to specify Type 3A vs Type 3 CRI on a project requisition.
ASTM Guide G101 publishes the Legault-Leckie empirical formula for atmospheric corrosion resistance of low-alloy structural steels, derived from extensive field exposure tests in industrial, marine and rural atmospheres. The formula is:
I = 26.01 (%Cu) + 3.88 (%Ni) + 1.20 (%Cr) + 1.49 (%Si) + 17.28 (%P) - 7.29 (%Cu)(%Ni) - 9.10 (%Ni)(%P) - 33.39 (%Cu)^2
Each element appears with its percentage by weight. The chromium, nickel, copper, silicon and phosphorus coefficients are positive (they improve corrosion resistance); the Cu-Ni, Ni-P, and Cu^2 cross-terms are negative (interactions between high-content elements reduce the marginal benefit).
Take a Type 3A washer at mid-band chemistry: Si 0.25, Cr 0.55, Ni 0.35, Cu 0.35, P 0.030. Compute Legault-Leckie:
| Term | Value | Contribution |
|---|---|---|
| 26.01 x 0.35 (Cu) | +9.10 | large positive |
| 3.88 x 0.35 (Ni) | +1.36 | moderate positive |
| 1.20 x 0.55 (Cr) | +0.66 | small positive |
| 1.49 x 0.25 (Si) | +0.37 | small positive |
| 17.28 x 0.030 (P) | +0.52 | small positive |
| -7.29 x 0.35 x 0.35 (Cu-Ni) | -0.89 | moderate negative |
| -9.10 x 0.35 x 0.030 (Ni-P) | -0.10 | small negative |
| -33.39 x 0.35^2 (Cu^2) | -4.09 | large negative |
| I (total) | +6.93 | passes CRI 6 cut-off |
Type 3A mid-band chemistry computes to I = 6.93, comfortably above the 6.0 threshold. The Cu^2 quadratic penalty at 0.35 percent Cu is roughly half the linear Cu credit, which is why Type 3A caps Cu at 0.45 — pushing higher does not improve corrosion resistance proportionately.
| Decision factor | Type 3A (fixed chemistry) | Type 3 CRI 6 (formula) |
|---|---|---|
| Project spec citation | "F436 Type 3A" or default Type 3 | "F436 Type 3 to CRI 6 minimum" |
| Chemistry verification | Single chemistry envelope check against Table 1 | Heat chemistry + formula computation on cert |
| Supplier flexibility | Lower (must hit narrow band) | Higher (wider chemistry as long as I >= 6) |
| Multi-source compatibility | Easier (everyone hits same band) | Requires CRI cert per heat from each source |
| Inspection workflow | Read chemistry table directly | Run Legault-Leckie computation; AS101 online calculator |
| Cost | Slightly higher (tighter band) | Slightly lower (wider chemistry options) |
For most refinery, bridge and transmission-tower projects, Type 3A fixed chemistry is the clearer call — every mill cert reads the same envelope and the project quality plan checks a single table. The CRI 6 option matters when (a) the project sources from multiple weathering-steel mills with slightly different chemistry recipes, (b) the project uses a non-standard weathering steel listed in A588 Table 2 (which F436 Note B permits), or (c) the design pre-existed and used the Legault-Leckie formula as its corrosion-resistance basis. In those cases, specifying "F436 Type 3 to CRI 6 or higher" gives the engineer flexibility without sacrificing the corrosion guarantee.
For full F436 Type 3 chemistry and the parent specification see F436 Type 3 washers. The hot-dip galvanizing alternative to weathering chemistry is on F436 hot-dip galvanizing F2329; choose between Type 3 weathering and HDG Type 1 based on whether direct atmospheric patina exposure is acceptable. For complete material specification background see F436 washer specifications.
CRI is the Corrosion Resistance Index computed from the Legault-Leckie empirical formula published in ASTM Guide G101. F436 Section 2.1 allows Type 3 weathering steel washers to be supplied to a CRI of 6 or higher as an alternative to the fixed Type 3A chemistry envelope in Table 1. The formula combines weighted contributions from Cu, Ni, Cr, Si and P with quadratic and cross-term penalties; a CRI value of 6 corresponds to approximately twice the atmospheric corrosion resistance of plain carbon steel under standard industrial-atmosphere exposure conditions.
Apply the Legault-Leckie formula I = 26.01(Cu) + 3.88(Ni) + 1.20(Cr) + 1.49(Si) + 17.28(P) - 7.29(Cu)(Ni) - 9.10(Ni)(P) - 33.39(Cu)^2 with each element percentage by weight from the heat-analysis chemistry. ASTM hosts an online spreadsheet calculator at G101 Calculator that performs the math. The result must be at least 6.0 for the heat to qualify as F436 Type 3 to CRI 6. TorqBolt mill certs list the heat chemistry, the computed CRI, and the calculator URL alongside the standard test results.
Type 3A and Type 3 CRI 6 produce similar mid-band CRI values (around 6.9 for Type 3A mid-band chemistry). Type 3A is the more conservative choice in the sense that every mill cert reads the same chemistry envelope, making project QA simpler. Type 3 CRI 6 is more flexible: a heat can vary chemistry within a wider band as long as the computed CRI clears 6.0. Both are equally compliant with F436; the choice is a project-management trade-off between flexibility and inspection simplicity.
Yes, but only if the resulting CRI is 6.0 or higher. F436 Note B permits Type 3 washers manufactured from any of the steels listed in A588 / A588M Table 2 and ASTM F3125, OR from any other steel chemistry that computes to a Legault-Leckie CRI of 6 or higher. This second clause lets a supplier use a non-standard alloy as long as the CRI computation is documented on the heat cert. The clause is rarely invoked because A588 chemistry is widely available; it exists for edge cases like recycled or salvaged-heat material.